Trisodium Citrate Dihydrate

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Trisodium Citrate Dihydrate
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Trisodium Citrate Dihydrate is the dihydrate form of trisodium citrate, supplied as a white crystalline powder or crystals. It is used as a buffering agent, acidity regulator, sequestrant and emulsifying salt in food and beverage formulations.
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Acidity Regulators
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Description

Trisodium Citrate Dihydrate is the dihydrate form of trisodium citrate, supplied as a white crystalline powder or crystals. It is used as a buffering agent, acidity regulator, sequestrant and emulsifying salt in food and beverage formulations. It is commonly supplied to food ingredient manufacturers, distributors and industrial buyers in bulk quantities. 

 

Product Specification

 

 

Item

Specification

Product Name

Trisodium Citrate Dihydrate

Chemical Formula

C₆H₅Na₃O₇·2H₂O

Molecular Weight

294.10

CAS No.

6132-04-3

EINECS No.

200-675-3

Appearance

White or colorless crystalline granules or powder

Odor

Odorless

Taste

Salty, cooling

pH

Meets specification

Assay / Content

99.0–100.5%

Light Transmittance

≥95.0%

Moisture

10.0–13.0%

Readily Carbonizable Substances

≤1.0%

Sulphate

≤0.01%

Chloride

≤0.005%

Oxalate

≤0.01%

Calcium Salts

≤0.02%

Iron Salts

≤5 mg/kg

Arsenic

≤1 mg/kg

Lead

≤2 mg/kg

 

Dihydrate vs. Anhydrous Comparison

 

 

Water of Crystallization: The dihydrate grade incorporates two moles of crystal water within its molecular structure, whereas the anhydrous variant contains no bound water molecules.

Thermal Behavior: Dihydrate crystals begin to lose their structural crystal water when heated to 150°C, a phase transition not required for the anhydrous form during processing.

Hygroscopic Tendency: The dihydrate version exhibits slight deliquescence when exposed to moist air, requiring distinct humidity controls compared to anhydrous forms.

Formulation Ratios: Dihydrogen and anhydrous variations require proportional adjustments in batch weighting due to the molecular weight difference introduced by the crystal water.

 

Functional Properties

 

 

PH Buffering Action: Acts as a reliable acidity regulator to stabilize pH levels in food and beverage formulations against shifting acidity.

Melting Emulsification: Functions effectively as an oil emulsifier in cheese processing, allowing proteins to maintain emulsion stability so cheese melts evenly without oil separation.

Flavor Modification: Contributes a clean, salty, and cooling flavor profile while simultaneously enhancing active ingredient stability in aqueous systems.

Chelating Capability: Binds trace metal ions in solution to prevent oxidative degradation and discoloration in processed foods and technical applications.

 

Application-Specific Module

 

 

Beverage Acidity Control: Applied as a buffering agent in soft drinks and functional beverages to adjust and maintain target acidity ranges.

Dairy Processing: Utilized in processed cheese manufacturing to prevent fat separation and achieve smooth textural melting properties.

Industrial Detergents: Deployed as a safe alternative to sodium tripolyphosphate in detergent formulations to soften water and boost cleaning efficiency.

Technical Synthesis: Utilized as a processing aid in industrial fermentation, chemical injection, photography development, and metal plating baths.

 

Applicable Standards & Compliance

 

 

E331(iii) Food Additive: Trisodium citrate is listed as E331(iii) for the tribasic sodium citrate form. EU specifications recognize trisodium citrate in anhydrous, dihydrate and pentahydrate forms.

EU Specification: EU E331(iii) specifies not less than 99% assay on an anhydrous basis, with pH 7.5–9.0 in a 5% aqueous solution and defined limits for loss on drying, oxalates, arsenic, lead and mercury.

USP Reference: USP identifies sodium citrate in anhydrous and dihydrate forms and specifies 99.0–100.5% sodium citrate calculated on the anhydrous substance. The dihydrate is identified by CAS No. 6132-04-3 and molecular weight 294.10.

 

Storage & Handling

 

 

Moisture Protection: Store in a tightly sealed container and protect the material from moisture. The product can be slightly deliquescent in moist air, so open packaging should not be left exposed during handling.

Storage Conditions: Keep in a cool, dry and well-ventilated area away from excessive heat and humidity.

Packaging: The supplied standard packaging is 25 kg net paper bags or jumbo bags with PE liners; customized packaging can be arranged according to customer requirements.

Heat Exposure: Trisodium citrate dihydrate can lose crystallization water when heated to around 150°C. Avoid unnecessary heat exposure during storage and handling.

 

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FAQ

 

 

Q: How should buyers compare quotations or COAs for dihydrate versus anhydrous grades?

A: Always verify whether the assay is reported on an anhydrous basis and check the hydration state to avoid misleading price or dosage comparisons by weight.

Q: Can you accommodate customized or private-label packaging?

A: Yes, custom-printed bags or specific net weights can be arranged upon agreement of minimum order quantities.

Q: What documents are included with each shipment?

A: Each dispatch includes a batch Certificate of Analysis (CoA), a Material Safety Data Sheet (MSDS), and standard shipping documents.

Q: What is the typical lead time for production and dispatch?

A: Orders are generally prepared and shipped within 10 to 15 days, depending on current plant scheduling and volume.

Q: Is third-party pre-shipment inspection accepted?

A: Yes, buyers can arrange independent inspection agencies like SGS or BV for on-site sampling prior to loading.

Q: What is the recommended shelf life under proper storage?

A: The product remains stable for up to 24 months when kept sealed in cool, dry warehouse conditions.

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